I haven’t stress tested it, but I just had a scene running to turn on all my lights when I’m in Home mode (based on geofencing) AND sunset switch turns to night. ;D
Edit:
Also managed to trigger it the other way around, sunset switch being in night status and then switching from Away to Home mode.
If you want any kind of complex logic (not just AND), it’s time to move to PLEG. You can still use the built in scenes if you wish, but you can trigger them from PLEG and use any logic you can assemble to control them.
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